- Schottky defect: Missing cations and anions → lowers density.
- Frenkel defect: Cation dislocation → density remains unchanged.
Step 1: Understanding Frenkel and Schottky defects. Frenkel and Schottky defects are two types of point defects that occur in crystalline solids.
- Schottky Defect:
- Occurs in ionic solids (e.g., NaCl, KCl).
- Equal number of cations and anions are missing from the crystal lattice.
- Results in a decrease in density of the crystal.
- Frenkel Defect:
- Occurs in ionic solids with large size differences between cations and anions (e.g., AgCl, ZnS). - A cation moves from its normal position to an interstitial site.
- Does not affect density.
Step 2: Identifying the correct classification. - These defects occur within the crystal structure, hence they are crystal defects. - They are not related to the nucleus or non-crystalline materials.
Final Answer: \[ \boxed{{Crystal defects}} \]