The rate law is given by:
\[
\text{Rate} = k[A]^2[B]
\]
Let's compare the initial rate with the rate after changing the concentrations.
- Initial concentration of A = \( [A] \), initial concentration of B = \( [B] \).
- New concentration of A = \( 2[A] \) (doubled), new concentration of B = \( \frac{1}{2}[B] \) (halved).
Substitute these into the rate law:
- Initial rate: \( \text{Rate}_\text{initial} = k[A]^2[B] \)
- New rate: \( \text{Rate}_\text{new} = k(2[A])^2\left(\frac{1}{2}[B]\right) \)
Simplifying:
\[
\text{Rate}_\text{new} = k \times 4[A]^2 \times \frac{1}{2}[B] = 2k[A]^2[B]
\]
Thus, the new rate is twice the initial rate, meaning the rate increases by a factor of 4.