For an nth order reaction (n ≠ 1), the half-life period (t1/2) is given by the formula:
\( t_{1/2} \propto \frac{1}{a^{n-1}} \)
where:
- \( a \) is the initial concentration
- \( n \) is the order of the reaction
Correct Answer: \( \frac{1}{a^{n-1}} \)
For an nth order reaction (where \( n \ne 1 \)), the expression for half-life is:
$$ t_{1/2} \propto \frac{1}{a^{n - 1}} $$
Here, \( a \) is the initial concentration. Therefore, the half-life is inversely proportional to \( a^{n - 1} \).
Correct answer: \( \frac{1}{a^{n - 1}} \)
A(g) $ \rightarrow $ B(g) + C(g) is a first order reaction.
The reaction was started with reactant A only. Which of the following expression is correct for rate constant k ?
Rate law for a reaction between $A$ and $B$ is given by $\mathrm{R}=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}[\mathrm{B}]^{\mathrm{m}}$. If concentration of A is doubled and concentration of B is halved from their initial value, the ratio of new rate of reaction to the initial rate of reaction $\left(\frac{\mathrm{r}_{2}}{\mathrm{r}_{1}}\right)$ is
For $\mathrm{A}_{2}+\mathrm{B}_{2} \rightleftharpoons 2 \mathrm{AB}$ $\mathrm{E}_{\mathrm{a}}$ for forward and backward reaction are 180 and $200 \mathrm{~kJ} \mathrm{~mol}^{-1}$ respectively. If catalyst lowers $\mathrm{E}_{\mathrm{a}}$ for both reaction by $100 \mathrm{~kJ} \mathrm{~mol}^{-1}$. Which of the following statement is correct?
The graph between variation of resistance of a wire as a function of its diameter keeping other parameters like length and temperature constant is
While determining the coefficient of viscosity of the given liquid, a spherical steel ball sinks by a distance \( x = 0.8 \, \text{m} \). The radius of the ball is \( 2.5 \times 10^{-3} \, \text{m} \). The time taken by the ball to sink in three trials are tabulated as shown: