The region \( D \) is described as the part of a sphere of radius \( a \) and centered at the origin, with the additional restriction that \( x^2 + y^2 \geq b^2 \), which means that the solid is bounded by a cylindrical hole along the \( z \)-axis.
To find the surface area of the boundary of the solid \( D \), we need to calculate the surface area of the sphere excluding the portion inside the cylinder.
The surface area of the sphere is given by \( 4\pi a^2 \). The region inside the cylinder can be described by the equation \( x^2 + y^2 = b^2 \), so the area of the spherical cap inside the cylinder is given by the formula for the surface area of a spherical zone, \( 2\pi (a^2 - b^2) \).
Thus, the surface area of the boundary of the solid \( D \) is the difference between the surface area of the entire sphere and the area inside the cylindrical hole, which is:
\[
4\pi (a + b)\sqrt{a^2 - b^2}.
\]
Therefore, the correct answer is (A): \( 4\pi(a + b)\sqrt{a^2 - b^2} \).