Step 1: Understanding BOF Method
The Basic Oxygen Furnace (BOF) process is a primary method used in steelmaking. In this process, pure oxygen is blown at high velocity over molten pig iron to oxidize impurities.
Step 2: Oxidation Sequence of Elements
In the BOF process, elements in the molten pig iron are oxidized based on their affinity for oxygen:
- Silicon has the highest affinity and gets oxidized first to form SiO\(_2\) (slag).
- Manganese and carbon are oxidized later as the reaction proceeds.
- Cadmium is not a major constituent in steel and is irrelevant in this context.
Step 3: Reaction of Silicon
\[
\text{Si} + \text{O}_2 \rightarrow \text{SiO}_2
\]
This reaction occurs at the initial stage of blowing due to silicon’s high reactivity.
Conclusion: The first element to be removed in the BOF process is silicon.