Step 1: What is Hoopes' Process?
Hoopes' process is an electrolytic refining method used for the purification of aluminium. It was developed by William Hoopes and is specifically used to obtain ultra-pure aluminium (about 99.99%).
Step 2: Working Principle
The setup involves:
- A three-layered cell:
- Top layer: Pure aluminium (cathode),
- Middle layer: Electrolyte (a mixture of molten salts like BaCl\(_2\), NaCl, and AlF\(_3\)),
- Bottom layer: Impure aluminium (anode).
When current is passed:
- Aluminium ions from the impure bottom layer migrate through the electrolyte and deposit as pure aluminium in the top layer.
Step 3: Elimination of Incorrect Options
- Copper: Refined using the electrolytic method, not Hoopes’.
- Lead ore: Concentration uses methods like froth flotation.
- Titanium: Refined using the Kroll process, not Hoopes’.
Conclusion: Hoopes’ process is used exclusively for the refining of aluminium.