Find the inverse of each of the matrices (if it exists). \(\begin{bmatrix}1&0&0\\3&3&0\\5&2&-1\end{bmatrix}\)
Let A=\(\begin{bmatrix}1&0&0\\3&3&0\\5&2&-1\end{bmatrix}\)
we have IAI=1(-3-0)-0+0=-3
now A11=-3-0=-3, A12=-(-3-0)=3, A13=6-15=9
A21=-(0-0)=0, A22=-1-0=-1,A23=-(2-0)=-2
A31=0-0=0,A32=-(0-0)=0,A33=3-0=3
therefore adj A=\(\begin{bmatrix}-3&0&0\\3&-1&0\\-9&-2&3\end{bmatrix}\)
so A-1=\(\frac{1}{\mid A \mid}\)adj A=\(-\frac{1}{3}\)\(\begin{bmatrix}-3&0&0\\3&-1&0\\-9&-2&3\end{bmatrix}\)
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.