To evaluate the integral \( \int_0^{\pi} \frac{x \sin x}{1 + \cos^2 x} \, dx \), we utilize symmetry and properties of trigonometric functions:
The function \(\sin x\) is symmetric around \(\frac{\pi}{2}\), and we can rewrite the integral as: \[ \int_0^{\pi} \frac{x \sin x}{1 + \cos^2 x} \, dx = \int_0^{\pi} \frac{(\pi - x) \sin x}{1 + \cos^2 x} \, dx \] Adding these two integrals: \[ 2 \int_0^{\pi} \frac{x \sin x}{1 + \cos^2 x} \, dx = \int_0^{\pi} \frac{\pi \sin x}{1 + \cos^2 x} \, dx \] \[ \int_0^{\pi} \frac{x \sin x}{1 + \cos^2 x} \, dx = \frac{\pi}{2} \int_0^{\pi} \frac{\sin x}{1 + \cos^2 x} \, dx \] The integral of \(\frac{\sin x}{1 + \cos^2 x}\) over \(0\) to \(\pi\) simplifies to half the integral over \(0\) to \(2\pi\) due to the periodicity and properties of \(\cos x\).
This complete integral from \(0\) to \(2\pi\) is known to result in \(\pi\), thus: \[ \int_0^{\pi} \frac{\sin x}{1 + \cos^2 x} \, dx = \frac{\pi}{2} \] Therefore: \[ \int_0^{\pi} \frac{x \sin x}{1 + \cos^2 x} \, dx = \frac{\pi}{2} \times \frac{\pi}{2} = \frac{\pi^2}{4}. \]
A solid is dissolved in 1 L water. The enthalpy of its solution (\(\Delta H_{{sol}}^\circ\)) is 'x' kJ/mol. The hydration enthalpy (\(\Delta H_{{hyd}}^\circ\)) for the same reaction is 'y' kJ/mol. What is lattice enthalpy (\(\Delta H_{{lattice}}^\circ\)) of the solid in kJ/mol?