Step 1: Recall that \(\sin^{-1} \left( -\frac{1}{2} \right)\) corresponds to an angle \(\theta\) such that \(\sin \theta = -\frac{1}{2}\) and \(\theta \in \left[ -\frac{\pi}{2}, \frac{\pi}{2} \right]\). From the unit circle, we know:
\[
\sin^{-1} \left( -\frac{1}{2} \right) = -\frac{\pi}{6}
\]
Step 2: Now evaluate:
\[
\frac{3\pi}{2} - \left( -\frac{\pi}{6} \right) = \frac{3\pi}{2} + \frac{\pi}{6}
\]
Step 3: Simplify the expression:
\[
\frac{3\pi}{2} + \frac{\pi}{6} = \frac{9\pi}{6} + \frac{\pi}{6} = \frac{10\pi}{6} = \pi
\]
Thus, the answer is \(\pi\).
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