Enthalpy of combustion
Enthalpy of fusion
The enthalpy of combustion is the heat change when one mole of a substance is completely burnt in excess oxygen under standard conditions.
This is an exothermic process, which means it releases heat to the surroundings.
Therefore, the enthalpy change (\( \Delta H \)) is always negative for combustion.
Enthalpy of combustion
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: