
The UV-visible spectrum of [Ni(en)\(_3\)]\(^{2+}\) (en = ethylenediamine) shows absorbance maxima at 11200 cm\(^{-1}\), 18350 cm\(^{-1}\), and 29000 cm\(^{-1}\).

[Given: Atomic number of Ni = 28] The correct match(es) between absorbance maximum and electronic transition is/are
Compound K displayed a strong band at 1680 cm−1 in its IR spectrum. Its 1H-NMR spectral data are as follows:
δ (ppm):
7.30 (d, J = 7.2 Hz, 2H)
6.80 (d, J = 7.2 Hz, 2H)
3.80 (septet, J = 7.0 Hz, 1H)
2.20 (s, 3H)
1.90 (d, J = 7.0 Hz, 6H)
The correct structure of compound K is:
Which one of the following graphs accurately represents the plot of partial pressure of CS₂ vs its mole fraction in a mixture of acetone and CS₂ at constant temperature?

In the given figure, the blocks $A$, $B$ and $C$ weigh $4\,\text{kg}$, $6\,\text{kg}$ and $8\,\text{kg}$ respectively. The coefficient of sliding friction between any two surfaces is $0.5$. The force $\vec{F}$ required to slide the block $C$ with constant speed is ___ N.
(Given: $g = 10\,\text{m s}^{-2}$) 