(i) Explain Kohlrausch's law. Write its applications.
Calculate the e.m.f. of the following cell: \[ \text{Cu(s)} | \text{Cu}^{2+} (1M) || \text{Ag}^{+} (0.01M) | \text{Ag(s)} \] Given: \[ E^0_{\text{Cu}^{2+}/\text{Cu}} = +0.34V, \quad E^0_{\text{Ag}^{+}/\text{Ag}} = +0.80V \]
Mention the events related to the following historical dates:
\[\begin{array}{rl} \bullet & 321 \,\text{B.C.} \\ \bullet & 1829 \,\text{A.D.} \\ \bullet & 973 \,\text{A.D.} \\ \bullet & 1336 \,\text{A.D.} \\ \bullet & 1605 \,\text{A.D.} \\ \bullet & 1875 \,\text{A.D.} \\ \bullet & 1885 \,\text{A.D.} \\ \bullet & 1907 \,\text{A.D.} \\ \bullet & 1942 \,\text{A.D.} \\ \bullet & 1935 \,\text{A.D.} \end{array}\]