Draw energy band diagrams of n-type and p-type semiconductors at temperature \( T>0 \, \text{K} \). Show the donor/acceptor energy levels with the order of difference of their energies from the bands.
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Donor levels in n-type semiconductors are close to the conduction band, while acceptor levels in p-type are close to the valence band, typically 0.01–0.05 eV apart, reflecting the ionization energies of impurities.
Part (a): Energy Band Diagram of an N-Type Semiconductor at \( T > 0\,\text{K} \)
N-type semiconductors are doped with donor impurities (e.g., phosphorus in silicon), introducing donor levels \( E_d \) just below the conduction band edge \( E_c \). At \( T > 0 \, \text{K} \), electrons are thermally excited from \( E_d \) to the conduction band, making electrons the majority carriers.
Step 1: Key Features
Valence Band: Filled up to \( E_v \)
Conduction Band: Starts at \( E_c \), with band gap \( E_g = E_c - E_v \) (e.g., 1.12 eV for silicon)
Donor Level: \( E_d \) is 0.01–0.05 eV below \( E_c \): \( E_c - E_d \approx 0.01 \text{ to } 0.05 \, \text{eV} \) (e.g., 0.045 eV for phosphorus in silicon)
Fermi Level: \( E_F \) lies between \( E_d \) and \( E_c \), closer to \( E_c \)
Carriers: Electrons in the conduction band, few holes in the valence band
Step 2: Diagram Description
Axes: Vertical energy axis (in eV)
Valence Band: Shaded region up to \( E_v \), labeled
Band Gap: Blank region of width \( E_g \)
Conduction Band: Unshaded region above \( E_c \), with light shading to indicate electrons
Donor Level: Dashed line at \( E_d \), 0.01–0.05 eV below \( E_c \), label \( E_c - E_d \)
Fermi Level: Dashed line at \( E_F \), between \( E_d \) and \( E_c \), closer to \( E_c \)
Part (b): Energy Band Diagram of a P-Type Semiconductor at \( T > 0\,\text{K} \)
P-type semiconductors are doped with acceptor impurities (e.g., boron in silicon), introducing acceptor levels \( E_a \) just above the valence band edge \( E_v \). At \( T > 0 \, \text{K} \), electrons from the valence band occupy \( E_a \), creating holes in the valence band.
Step 1: Key Features
Valence Band: Up to \( E_v \), with holes
Conduction Band: Starts at \( E_c \), with band gap \( E_g \)
Acceptor Level: \( E_a \) is 0.01–0.05 eV above \( E_v \): \( E_a - E_v \approx 0.01 \text{ to } 0.05 \, \text{eV} \) (e.g., 0.045 eV for boron in silicon)
Fermi Level: \( E_F \) lies between \( E_v \) and \( E_a \), closer to \( E_v \)
Carriers: Holes in the valence band, few electrons in the conduction band
Step 2: Diagram Description
Axes: Vertical energy axis (in eV)
Valence Band: Shaded region up to \( E_v \), with gaps indicating holes
Band Gap: Blank region of width \( E_g \)
Conduction Band: Unshaded region above \( E_c \), with minimal electron shading
Acceptor Level: Dashed line at \( E_a \), 0.01–0.05 eV above \( E_v \), label \( E_a - E_v \)
Fermi Level: Dashed line at \( E_F \), between \( E_v \) and \( E_a \), closer to \( E_v \)