Definition of Electrochemical Series:
The electrochemical series is a list of standard electrode potentials \( (E^\circ) \) of elements arranged in order of increasing or decreasing ability to lose or gain electrons.
Applications of the Electrochemical Series:
Standard electrode potential for \( \text{Sn}^{4+}/\text{Sn}^{2+} \) couple is +0.15 V and that for the \( \text{Cr}^{3+}/\text{Cr} \) couple is -0.74 V. The two couples in their standard states are connected to make a cell. The cell potential will be:
To calculate the cell potential (\( E^\circ_{\text{cell}} \)), we use the standard electrode potentials of the given redox couples.
Given data:
\( E^\circ_{\text{Sn}^{4+}/\text{Sn}^{2+}} = +0.15V \)
\( E^\circ_{\text{Cr}^{3+}/\text{Cr}} = -0.74V \)
(a.)Write the anode and cathode reactions and the overall cell reaction occurring in a lead storage battery during its use.
Mention the number of unpaired electrons and geometry of the following complexes:
(i) \([NiCl_4]^{2-}\)
(ii) \([Ni(CN)_4]^{2-}\)
Convert the following:
(a) Ethanenitrile into ethanal.
(b) Cyclohexane into adipic acid.