Question:

Cuprous ion is colourless while cupric ion is coloured because:

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A complete d-orbital configuration prevents d-d transitions, making the ion colourless.
Updated On: Apr 2, 2025
  • Both have half-filled p- and d-orbitals.
  • Cuprous ion has an incomplete d-orbital and cupric ion has a complete d-orbital.
  • Both have unpaired electrons in the d-orbitals.
  • Cuprous ion has a complete d-orbital and cupric ion has an incomplete d-orbital.
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The Correct Option is D

Solution and Explanation

Step 1: Understanding electronic configurations.
- \( Cu^+ \) has a complete 3d\(^{10}\) configuration (no d-d transitions, thus colourless).
- \( Cu^{2+} \) has a 3d\(^9\) configuration (allows d-d transitions, thus coloured).
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