Given: The internal energy is defined as \( U = A p^2 V \), where \( A \) is a constant. The process is performed adiabatically, and we are tasked with finding the relationship between pressure \( p \) and volume \( V \) during this process.
Approach: For an adiabatic process, the first law of thermodynamics tells us that the change in internal energy is equal to the work done: \[ dU = -PdV. \] This equation implies that: \[ A p^2 dV + 2A p V dp = -p dV. \] From this, we can derive a relationship between pressure and volume for an adiabatic process. Since we know the form of the internal energy \( U = A p^2 V \), we can proceed to find the specific relationship between \( p \) and \( V \) under the condition that the process is adiabatic.
Solution: Rearranging terms and solving the equation for an adiabatic process, we find that the relationship between \( p \) and \( V \) is: \[ (AP + 1)^2 V = \text{Constant}. \]
Final Answer: The correct relationship is \( (AP + 1)^2 V = \text{Constant} \).
The standard heat of formation, in kcal/mol, of $Ba^{2+}$ is:
Given: Standard heat of formation of SO₄²⁻(aq) = -216 kcal/mol, standard heat of crystallization of BaSO₄(s) = -4.5 kcal/mol, standard heat of formation of BaSO₄(s) = -349 kcal/mol.
A quantity \( X \) is given by: \[ X = \frac{\epsilon_0 L \Delta V}{\Delta t} \] where:
- \( \epsilon_0 \) is the permittivity of free space,
- \( L \) is the length,
- \( \Delta V \) is the potential difference,
- \( \Delta t \) is the time interval.
The dimension of \( X \) is the same as that of: