Question:

Concentrated H\(_2\)SO\(_4\) reacts with PCl\(_5\) to produce

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When sulfuric acid reacts with PCl\(_5\), sulfuryl chloride (SO\(_2\)Cl\(_2\)) and phosphorus oxychloride (POCl\(_3\)) are typically formed.
Updated On: Jan 30, 2026
  • HClO\(_2\)
  • SO\(_2\)Cl\(_2\)
  • SOCl\(_2\)
  • HClO\(_4\)
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The Correct Option is B

Solution and Explanation

Step 1: Understanding the reaction.
Concentrated sulfuric acid (H\(_2\)SO\(_4\)) reacts with phosphorus pentachloride (PCl\(_5\)) to produce sulfuryl chloride (SO\(_2\)Cl\(_2\)) and phosphorus oxychloride (POCl\(_3\)).

Step 2: Analyzing the options.
(A) HClO\(_2\): This compound is not formed in the reaction with PCl\(_5\).
(B) SO\(_2\)Cl\(_2\): Correct — This is sulfuryl chloride, the product of the reaction.
(C) SOCl\(_2\): This is thionyl chloride, but it is not the product of this reaction.
(D) HClO\(_4\): This is perchloric acid, which is not formed in this reaction.

Step 3: Conclusion.
The correct answer is (B) SO\(_2\)Cl\(_2\), which is formed in the reaction between concentrated H\(_2\)SO\(_4\) and PCl\(_5\).
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