Choose the correct answer.
If x,y,z are nonzero real numbers,then the inverse of matrix
A=\(\begin{bmatrix}x& 0& 0\\ 0& y& 0\\0&0& z\end{bmatrix}\)is
\(\begin{bmatrix}x^{-1}& 0& 0\\ 0& y^{-}1& 0\\0&0& z^{-1}\end{bmatrix}\)
xyz\(\begin{bmatrix}x^{-1}& 0& 0\\ 0& y^{-}1& 0\\0&0& z^{-1}\end{bmatrix}\)
\(\frac{1}{xyz}\begin{bmatrix}x& 0& 0\\ 0& y& 0\\0&0& z\end{bmatrix}\)
\(\frac{1}{xyz}\begin{bmatrix}1& 0& 0\\ 0& 1& 0\\0&0& 1\end{bmatrix}\)
A=\(\begin{bmatrix}x& 0& 0\\ 0& y& 0\\0&0& z\end{bmatrix}\)
\(∴|A|=x(yz-0)=xyz≠0\)
Now,
\(A_{11}=yz,A_{12}=0,A_{13}=0\)
\(A_{21}=0,A_{22}=xz,A_{23}=0\)
\(A_{31}=0,A_{32}=0,A_{33}=xy\)
\(∴adjA\)=\(\begin{bmatrix}yz& 0& 0\\ 0& xz& 0\\0&0& xy\end{bmatrix}\)
\(∴A^{-1}\)=\(\frac{1}{|A|}\)\(adjA\)
=\(\frac{1}{xyz}\begin{bmatrix}yz& 0& 0\\ 0& xz& 0\\0&0& xy\end{bmatrix}\)
=\(\begin{bmatrix}\frac{yz}{xyz}& 0& 0\\ 0& \frac{xz}{xyz}& 0\\0&0& \frac{xy}{xyz}\end{bmatrix}\)
=\(\begin{bmatrix}\frac{1}{x}& 0& 0\\ 0& \frac{1}{y}& 0\\0&0& \frac{1}{z}\end{bmatrix}\)
=\(\begin{bmatrix}x^{-1}& 0& 0\\ 0& y^{-1}& 0\\0&0& z^{-1}\end{bmatrix}\)
The correct answer is A.
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.