Step 1: Reflexivity
For \( a \in \mathbb{R} \):
\[
a - a + \sqrt{2} = \sqrt{2} \text{ is irrational.}
\]
Thus, \( (a, a) \in S \), and \( S \) is reflexive.
Step 2: Symmetry
Let \( (a, b) \in S \), so:
\[
a - b + \sqrt{2} \text{ is irrational.}
\]
Now, check if \( (b, a) \in S \):
\[
b - a + \sqrt{2} \text{ may or may not be irrational.}
\]
For example:
\[
a = \sqrt{2}, \, b = 1 \implies a - b + \sqrt{2} = \sqrt{2} - 1 + \sqrt{2} = 2\sqrt{2} - 1 \text{ (irrational), but}
\]
\[
b - a + \sqrt{2} = 1 - \sqrt{2} + \sqrt{2} = 1 \text{ (rational).}
\]
Thus, \( S \) is not symmetric.
Step 3: Transitivity
Let \( (a, b) \in S \) and \( (b, c) \in S \), so:
\[
a - b + \sqrt{2} \text{ is irrational, and } b - c + \sqrt{2} \text{ is irrational.}
\]
Check if \( (a, c) \in S \):
\[
a - c + \sqrt{2} = (a - b + \sqrt{2}) + (b - c + \sqrt{2}) - \sqrt{2} \text{ may or may not be irrational.}
\]
For example:
\[
a = 1, b = \sqrt{3}, c = \sqrt{3} - \sqrt{2} \implies a - c + \sqrt{2} = 1 - (\sqrt{3} - \sqrt{2}) + \sqrt{2} = 1 - \sqrt{3} + 2\sqrt{2}.
\]
This is irrational, but a counterexample exists for other values. Thus, \( S \) is not transitive.
Step 4: Final Conclusion
The relation \( S \) is reflexive but neither symmetric nor transitive.