Question:

Calculate the pressure of gas if the solubility of gas in water at 25°C is 6.85 x 10–4 mol.dm–3. (Henry’s law constant is 6.85 x 10–4 mol.dm–3.bar–1)

Updated On: Apr 14, 2025
  • 0.5 bar
  • 1 bar

  • 1.5 bar
  • 2.0 bar
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The Correct Option is B

Solution and Explanation

Concept Used: Henry’s Law

Henry’s Law relates the solubility of a gas in a liquid to the pressure of the gas above the liquid. It is mathematically represented as:

S = KH × P

Where:

  • S = solubility of gas (mol·dm–3)
  • KH = Henry’s law constant (mol·dm–3·bar–1)
  • P = pressure of the gas (bar)

 

Step-by-Step Solution:

Given:

  • Solubility, S = 6.85 × 10–4 mol·dm–3
  • Henry’s Law Constant, KH = 6.85 × 10–4 mol·dm–3·bar–1

Using Henry’s Law:

S = KH × P

Rearranging the formula to find pressure (P):

P = S / KH

Substitute the values:

P = (6.85 × 10–4) / (6.85 × 10–4)

P = 1 bar

Final Answer: Option 2: 1 bar

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