Step 1: Understanding the work done in an isothermal process.
The work done (\(W\)) during an isothermal expansion is given by the equation:
\[
W = -P_{\text{ext}} \Delta V
\]
Where:
- \(P_{\text{ext}} = 3 \, \text{atm}\) (external pressure)
- \(\Delta V = V_2 - V_1 = 6 \, \text{dm}^3 - 4 \, \text{dm}^3 = 2 \, \text{dm}^3\)
- To convert atm·dm\(^3\) to joules, we use the conversion factor:
\[
1 \, \text{atm} \cdot \text{dm}^3 = 101.325 \, \text{J}
\]
Step 2: Calculating the work.
\[
W = - (3 \, \text{atm}) \times (2 \, \text{dm}^3) \times (101.325 \, \text{J/atm·dm}^3) = -607.8 \, \text{J}
\]
Step 3: Conclusion.
The correct answer is (C) -607.8 J.