Maltose is a disaccharide formed from two \(\alpha\)-D-glucose units. The glycosidic bond is formed between the C-1 of one glucose and C-4 of the other. Importantly:
- One of the glucose units retains a free hemiacetal (anomeric) carbon.
- This allows maltose to act as a reducing sugar.
Thus:
- Assertion is correct — maltose is indeed a reducing sugar.
- Reason is also correct — the linkage involves C-1 to C-4.
- Since the glycosidic linkage does not involve both anomeric carbons (unlike in sucrose), the free anomeric carbon enables reducing behavior.
\[
\boxed{\text{Both A and R are true and R is the correct explanation of A.}}
\]