Assertion (A): All naturally occurring \(\alpha\)-amino acids except glycine are optically active. Reason (R): Most naturally occurring amino acids have L-configuration.
Assertion (A) is false, but Reason (R) is true.
Step 1: Understanding optical activity of amino acids. All naturally occurring \(\alpha\)-amino acids, except for glycine, are optically active because they contain a chiral carbon atom (except glycine which has two hydrogen atoms on the chiral center, making it achiral).
Step 2: L-configuration of amino acids. Most naturally occurring amino acids are in the L-configuration, which is why they are optically active (except glycine).
Step 3: Conclusion. Thus, both Assertion (A) and Reason (R) are true, and Reason (R) correctly explains Assertion (A), making option (A) the correct answer. \vspace{10pt}
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.