Baking soda (NaHCO3) acts as an anti-acid due to its ability to neutralize excess stomach acid. When baking soda reacts with hydrochloric acid (HCl) in the stomach, it produces sodium chloride (NaCl), carbon dioxide (CO2), and water (H2O), which relieves the acidity. The chemical equation is:
\[
NaHCO_3 (aq) + HCl (aq) \rightarrow NaCl (aq) + CO_2 (g) + H_2O (l)
\]
Thus, the chemical property utilized here is its ability to neutralize acids.