Question:

An unknown alcohol is treated with "Lucas reagent" to determine whether the alcohol is primary, secondary, or tertiary. Which alcohol reacts fastest and by what mechanism?

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Lucas reagent test works on carbocation stability, making tertiary alcohols the fastest-reacting.
Updated On: Mar 25, 2025
  • Secondary alcohol by SN₁
  • Tertiary alcohol by SN₁
  • Secondary alcohol by SN₂
  • Tertiary alcohol by SN₂
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The Correct Option is B

Solution and Explanation

Step 1: Understanding Lucas Test
- Lucas test differentiates alcohols based on their reaction with ZnCl2/HCl.
Step 2: Order of Reactivity
- Tertiary alcohols react fastest via the SN1 mechanism.
Final Answer: Tertiary alcohol via SN1.

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