Specific wavelength at which extinction coefficient of a component is zero
Step 1: Understanding the concept of the isosbestic point. - An isosbestic point occurs when the absorbance of a mixture remains constant despite changes in concentration of two or more components. - This indicates that at a specific wavelength, the total absorptivity remains unchanged.
Step 2: Explanation of incorrect options.
- (A) Specific wavelength at which a single component has maximum absorptivity: Incorrect, because an isosbestic point involves two or more components, not a single component.
- (B) Specific wavelength at which the solvent has maximum absorptivity: Incorrect, as the isosbestic point is related to solute absorbance, not solvent.
- (D) Specific wavelength at which extinction coefficient of a component is zero: Incorrect, because extinction coefficients are nonzero at isosbestic points.
Step 3: Selecting the correct option. Since an isosbestic point is defined as a wavelength where two or more components have identical absorptivity, the correct answer is (C) Specific wavelength at which two or more components have the same absorptivity.
The UV-visible spectrum of [Ni(en)\(_3\)]\(^{2+}\) (en = ethylenediamine) shows absorbance maxima at 11200 cm\(^{-1}\), 18350 cm\(^{-1}\), and 29000 cm\(^{-1}\).
[Given: Atomic number of Ni = 28] The correct match(es) between absorbance maximum and electronic transition is/are
Compound K displayed a strong band at 1680 cm−1 in its IR spectrum. Its 1H-NMR spectral data are as follows:
δ (ppm):
7.30 (d, J = 7.2 Hz, 2H)
6.80 (d, J = 7.2 Hz, 2H)
3.80 (septet, J = 7.0 Hz, 1H)
2.20 (s, 3H)
1.90 (d, J = 7.0 Hz, 6H)
The correct structure of compound K is:
The 1H NMR spectrum of the given iridium complex at room temperature gave a single signal at 2.6 ppm, and its 31P NMR spectrum gave a single signal at 23.0 ppm. When the spectra were recorded at lower temperatures, both these signals split into a complex pattern. The intra-molecular dynamic processes shown by this molecule are:
A closed-loop system has the characteristic equation given by: $ s^3 + k s^2 + (k+2) s + 3 = 0 $.
For the system to be stable, the value of $ k $ is:
A digital filter with impulse response $ h[n] = 2^n u[n] $ will have a transfer function with a region of convergence.