Specific wavelength at which extinction coefficient of a component is zero
Step 1: Understanding the concept of the isosbestic point. - An isosbestic point occurs when the absorbance of a mixture remains constant despite changes in concentration of two or more components. - This indicates that at a specific wavelength, the total absorptivity remains unchanged.
Step 2: Explanation of incorrect options.
- (A) Specific wavelength at which a single component has maximum absorptivity: Incorrect, because an isosbestic point involves two or more components, not a single component.
- (B) Specific wavelength at which the solvent has maximum absorptivity: Incorrect, as the isosbestic point is related to solute absorbance, not solvent.
- (D) Specific wavelength at which extinction coefficient of a component is zero: Incorrect, because extinction coefficients are nonzero at isosbestic points.
Step 3: Selecting the correct option. Since an isosbestic point is defined as a wavelength where two or more components have identical absorptivity, the correct answer is (C) Specific wavelength at which two or more components have the same absorptivity.

The UV-visible spectrum of [Ni(en)\(_3\)]\(^{2+}\) (en = ethylenediamine) shows absorbance maxima at 11200 cm\(^{-1}\), 18350 cm\(^{-1}\), and 29000 cm\(^{-1}\).

[Given: Atomic number of Ni = 28] The correct match(es) between absorbance maximum and electronic transition is/are
If A + B means A is the mother of B; A - B means A is the brother of B; A % B means A is the father of B, and A \(\times\) B means A is the sister of B, which of the following shows that P is the maternal uncle of Q?