An increase in the concentration of the reactants of a reaction leads to change in :
- activation energy
- heat of reaction
- threshold energy
- collision frequency
The Correct Option is D
Solution and Explanation
As concentraction o f reactants o f a reaction increase the number of reactant molecules per unit volume increase which increases the collision frequency
Top Questions on Equilibrium Constant
- In which of the following equilibria, Kp and Ke are NOT equal?
- NEET (UG) - 2024
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- At \(298\ K\)
\(N_2( g)+3H_2( g)⇌2NH_3( g),K_1=4×10^5\)
\(N_2( g)+O_2( g)⇌2NO(g),K_2=1.6×10^{12}\)
\(H_2( g)+1 2O_2( g)⇌H_2O(g),K_3=1.0×10^{−13}\)
Based on above equilibria, the equilibrium constant of the reaction,
\(2NH_3( g)\)+\(\frac5 {2}\) \(O_2( g)⇌2NO(g)+3H_2O(g)\) is _______ \(×10^{−33 }\). (Nearest integer)- JEE Main - 2023
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\(Zn(s)+Sn^{2+}(aq)⇌Zn^{2+}(aq)+Sn(s)\, is\, 1×10^{20}\) at \(298 K\).
The magnitude of standard electrode potential of \(Sn/Sn^{2+}\) if \(E^{\degree}_{ Zn^{2+}/Zn}= –0.76V \) is _______ \(×10^{−2} V\). (Nearest integer).
(Given : \(\frac{2.303RT}{ F}\) \(=0.059 V \))- JEE Main - 2023
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- At \(298\ K\), the equilibrium constant is \(2 × 10^{15}\) for the reaction:
\(Cu(s)+2Ag+(Aq)⇌Cu^{2+}(aq)+2Ag(s)\)
The equilibrium constant for the reaction:
\(\frac 12Cu^{2+}(aq)+Ag(s)+(Aq)⇌\frac 12Cu(s)+Ag^+(aq)\) is \(x \times10^{-8}\).
The value of \(x\) is ______ . (Nearest integer)- JEE Main - 2022
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- \(PCl_5\) dissociates as
\(PCl_5(g) ⇌ PCl_3(g)+ Cl_2(g)\)
\(5\) moles of \(PCl_5\) are placed in a \(200\) litre vessel which contains \(2\) moles of \(N_2\) and is maintained at \(600\ K\). The equilibrium pressure is \(2.46\) atm. The equilibrium constant Kp for the dissociation of \(PCl_5\) is ______ \(× 10^{–3}\). (nearest integer)
(Given: \(R = 0.082\) L atm K–1 mol–1; Assume ideal gas behaviour)- JEE Main - 2022
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Assertion A : The potential (V) at any axial point, at 2 m distance(r) from the centre of the dipole of dipole moment vector \(\vec{P}\) of magnitude, 4 × 10-6 C m, is ± 9 × 103 V.
(Take \(\frac{1}{4\pi\epsilon_0}=9\times10^9\) SI units)
Reason R : \(V=±\frac{2P}{4\pi \epsilon_0r^2}\), where r is the distance of any axial point, situated at 2 m from the centre of the dipole.
In the light of the above statements, choose the correct answer from the options given below :- NEET (UG) - 2024
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Statement II: Inner membrane of mitochondria is relatively less permeable, as compared chloroplast. I
In the light of the above statements, choose the mis appropriate answer from the options given below- NEET (UG) - 2024
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List I
List II
A Mesozoic Era I Lower invertebrates B Proterozoic Era II Fish & Amphibia C Cenozoic Era III Birds & Reptiles D Paleozoic Era IV Mammals - NEET (UG) - 2024
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Concepts Used:
Equilibrium Constant
The equilibrium constant may be defined as the ratio between the product of the molar concentrations of the products to that of the product of the molar concentrations of the reactants with each concentration term raised to a power equal to the stoichiometric coefficient in the balanced chemical reaction.
The equilibrium constant at a given temperature is the ratio of the rate constant of forwarding and backward reactions.
Equilibrium Constant Formula:
Kequ = kf/kb = [C]c [D]d/[A]a [B]b = Kc
where Kc, indicates the equilibrium constant measured in moles per litre.
For reactions involving gases: The equilibrium constant formula, in terms of partial pressure will be:
Kequ = kf/kb = [[pC]c [pD]d]/[[pA]a [pB]b] = Kp
Where Kp indicates the equilibrium constant formula in terms of partial pressures.
- Larger Kc/Kp values indicate higher product formation and higher percentage conversion.
- Lower Kc/Kp values indicate lower product formation and lower percentage conversion.
Medium Kc/Kp values indicate optimum product formation.
Units of Equilibrium Constant:
The equilibrium constant is the ratio of the concentrations raised to the stoichiometric coefficients. Therefore, the unit of the equilibrium constant = [Mole L-1]△n.
where, ∆n = sum of stoichiometric coefficients of products – a sum of stoichiometric coefficients of reactants.