The efficiency of a Carnot engine is given by: \[ \eta = 1 - \frac{T_{\text{cold}}}{T_{\text{hot}}} \] where \( T_{\text{hot}} = 127(^\circ)C = 127 + 273 = 400 \, \text{K} \) and \( T_{\text{cold}} = 27(^\circ)C = 27 + 273 = 300 \, \text{K} \). \[ \eta = 1 - \frac{300}{400} = 0.25 \] The work done by the engine is: \[ W = \eta Q_{\text{in}} = 0.25 \times 5 \times 10^4 = 1.25 \times 10^4 \, \text{cal} \] Thus, the amount of heat converted to work is \( 1.25 \times 10^4 \, \text{cal} \).
A sample of n-octane (1.14 g) was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is 5 kJ K\(^{-1}\). As a result of combustion, the temperature of the calorimeter increased by 5 K. The magnitude of the heat of combustion at constant volume is ___
A perfect gas (0.1 mol) having \( \bar{C}_V = 1.50 \) R (independent of temperature) undergoes the above transformation from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is ____ J (nearest integer) [Given : R = 0.082 L atm K\(^{-1}\)] 
If the roots of $\sqrt{\frac{1 - y}{y}} + \sqrt{\frac{y}{1 - y}} = \frac{5}{2}$ are $\alpha$ and $\beta$ ($\beta > \alpha$) and the equation $(\alpha + \beta)x^4 - 25\alpha \beta x^2 + (\gamma + \beta - \alpha) = 0$ has real roots, then a possible value of $y$ is: