Step 1: The de-Broglie wavelength \( \lambda \) of a particle is given by: \[ \lambda = \frac{h}{mv}, \] where \( h \) is Planck's constant, \( m \) is the mass of the particle, and \( v \) is its velocity.
Step 2: For a photon, the de-Broglie wavelength is related to its momentum \( p \) by: \[ \lambda = \frac{h}{p} = \frac{h}{E/c}, \] where \( E \) is the energy of the photon and \( c \) is the speed of light.
Step 3: Given that the electron and photon have the same de-Broglie wavelength, we equate the expressions for \( \lambda \) for both: \[ \frac{h}{mv} = \frac{h}{E/c}. \] Simplifying: \[ mv = E/c. \]
Step 4: The energy of the electron is its kinetic energy \( K_e = \frac{1}{2}mv^2 \), and the energy of the photon is \( E = hf \), where \( f \) is the frequency of the photon.
Step 5: From the relation \( mv = E/c \), the ratio of the kinetic energy of the electron to the energy of the photon can be written as: \[ \frac{K_e}{E} = \frac{v}{2c}. \]
Arrange the following halides in decreasing order of their reactivity towards dehydrohalogenation: