Question:
An alkali metal hydride $(NaH)$ reacts with diborane in $A$ to give a tetrahedral compound $B$ which is extensively used as reducing agent in organic synthesis. The compounds $A$ and $B$ respectively are
An alkali metal hydride $(NaH)$ reacts with diborane in $A$ to give a tetrahedral compound $B$ which is extensively used as reducing agent in organic synthesis. The compounds $A$ and $B$ respectively are
Updated On: Apr 2, 2024
- $C_2H_6$ and $C_2H_5Na$
- $CH_3COCH_3$ and $B_3N_3H_6$
- $C_6H_6$ and $NaBH_4$
- $(C_2H_5)_2O$ and $NaBH_4$
Hide Solution
Verified By Collegedunia
The Correct Option is D
Solution and Explanation
Sodium hydride NaH reacts with diborane in diethylether to give tetrahydridoborates, i.e. sodium borohydride which is used as reducing agent in organic synthesis.
$\underset{\text{Sodmm hydnde }}{{2NaH}} +\underset{\text{Diboran}}{{B_2H_6}} { ->[{Diethyl}][{ether}] A} \underset{\text{Sodium borohydride B}}{{2Na^+[BH_4]^-]}}$
A=diethyl ether $\left( C _{2} H _{5}\right)_{2} O$ B= Sodium borohydride $NaBH _{4}$
Was this answer helpful?
0
0
Top Questions on p -Block Elements
- $\textbf{Choose the correct statements about the hydrides of group 15 elements.}$
A. The stability of the hydrides decreases in the order \(\text{NH}_3 > \text{PH}_3 > \text{AsH}_3 > \text{SbH}_3 > \text{BiH}_3\)
B. The reducing ability of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
C. Among the hydrides, \(\text{NH}_3\) is a strong reducing agent while \(\text{BiH}_3\) is a mild reducing agent.
D. The basicity of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
Choose the most appropriate from the option given below:- JEE Main - 2024
- Chemistry
- p -Block Elements
- Identify the correct statements about p-block elements and their compounds.
(A) Non metals have higher electronegativity than metals.
(B) Non metals have lower ionisation enthalpy than metals.
(C) Compounds formed between highly reactive nonmetals and highly reactive metals are generally ionic.
(D) The non-metal oxides are generally basic in nature.
(E) The metal oxides are generally acidic or neutral in nature.- JEE Main - 2024
- Chemistry
- p -Block Elements
- $\textbf{Reduction potential of ions are given below:}$
\[ \begin{array}{ccc} \text{ClO}_4^- & \text{IO}_4^- & \text{BrO}_4^- \\ E^\circ = 1.19 \, \text{V} & E^\circ = 1.65 \, \text{V} & E^\circ = 1.74 \, \text{V} \\ \end{array} \]
The correct order of their oxidising power is:- JEE Main - 2024
- Chemistry
- p -Block Elements
The number of oxygen atoms present in chemical formula of fuming sulphuric acid is _______.
- JEE Main - 2024
- Chemistry
- p -Block Elements
- Taking stability as the factor, which one of the following represents correct relationship?
- NEET (UG) - 2023
- Chemistry
- p -Block Elements
View More Questions
Questions Asked in KCET exam
- Ten identical cells each emf 2V and internal resistance 1Ω are connected in series with two cells wrongly connected. A resistor of 10Ω is connected to the combination. What is the current through the resistor?
- KCET - 2023
- Cells in Series and in Parallel
- The speed of sound in an ideal gas at a given temperature T is v. The rms speed of gas molecules at that temperature is vrms. The ratio of the velocities v and vrms for helium and oxygen gases are X and X' respectively. Then \(\frac{X}{X'}\) is equal to
- KCET - 2023
- Thermodynamics
- If \(p(\frac{1}{q}+\frac{1}{r}),q(\frac{1}{r}+\frac{1}{p}),r(\frac{1}{p}+\frac{1}{q})\) are in A.P., then p, q, r
- KCET - 2023
- Arithmetic Progression
- A stretched wire of a material whose Young's modulus Y = 2 × 1011 Nm-2 has Poisson's ratio of 0.25. Its lateral strain εl = 10-3. The elastic energy density of the wire is
- KCET - 2023
- mechanical properties of solids
- A metallic rod of length 1 m held along east-west direction is allowed to fall down freely. Given horizontal component of earth’s magnetic field BH = 3 × 10-5 T. The emf induced in the rod at an instant t = 2s after it is released is ( Take g = 10 ms-2 )
- KCET - 2023
- Faradays laws of induction
View More Questions
Concepts Used:
P-Block Elements
- P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
- P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.
P block elements consist of:
- Group 13 Elements: Boron family
- Group 14 Elements: Carbon family
- Group 15 Elements: Nitrogen family
- Group 16 Elements: Oxygen family
- Group 17 Elements: Fluorine family
- Group 18 Elements: Neon family