Accomplish the following conversions:
(i) Nitrobenzene to benzoic acid
(ii) Benzene to m-bromophenol
(iii) Benzoic acid to aniline
(iv) Aniline to 2,4,6-tribromofluorobenzene
(v) Benzyl chloride to 2-phenylethanamine
(vi) Chlorobenzene to p-chloroaniline
(vii) Aniline to p-bromoaniline
(viii) Benzamide to toluene
(ix) Aniline to benzyl alcohol.
Accomplish the following conversions:
(i) Nitrobenzene to benzoic acid
(ii) Benzene to m-bromophenol
(iii) Benzoic acid to aniline
(iv) Aniline to 2,4,6-tribromofluorobenzene
(v) Benzyl chloride to 2-phenylethanamine
(vi) Chlorobenzene to p-chloroaniline
(vii) Aniline to p-bromoaniline
(viii) Benzamide to toluene
(ix) Aniline to benzyl alcohol.
Solution and Explanation
Top Questions on Amines
- An organic compound (P) on treatment with aqueous ammonia under hot condition forms compound (Q) which on heating with Br₂ and KOH forms compound (R) having molecular formula C₆H₇N. Names of P, Q and R respectively are.
- Benzene undergoes the following sequence of reactions:
- Statement-I : $\text{KMnO}_4 \xrightarrow{\Delta} \text{NH}_2$ followed by $\text{Br}_2/\text{KOH} \rightarrow \text{NH}_2$.
Statement-II : $\text{CH}_3\text{NH}_2 \xrightarrow{(i) \text{ Br}_2/\text{H}_2\text{O}, (ii) \text{ NaNO}_2/\text{HCl}, (iii) \text{ H}_3\text{PO}_2/\Delta} \text{CH}_3\text{Br}$. - Which of the following reaction is correctly matched with their product ?
- Observe the following reaction sequence:
\text{(P) }\xrightarrow{\text{NH}_3, \Delta} \text{(Q)} \xrightarrow{\text{Br}_2, \text{KOH}} \text{(R)}
Which of the following is the correct structure for P, Q, and R?
Questions Asked in CBSE CLASS XII exam
Rishika and Shivika were partners in a firm sharing profits and losses in the ratio of 3 : 2. Their Balance Sheet as at 31st March, 2024 stood as follows:
Balance Sheet of Rishika and Shivika as at 31st March, 2024Liabilities Amount (₹) Assets Amount (₹) Capitals: Equipment 45,00,000 Rishika – ₹30,00,000
Shivika – ₹20,00,00050,00,000 Investments 5,00,000 Shivika’s Husband’s Loan 5,00,000 Debtors 35,00,000 Creditors 40,00,000 Stock 8,00,000 Cash at Bank 2,00,000 Total 95,00,000 Total 95,00,000 The firm was dissolved on the above date and the following transactions took place:
(i) Equipements were given to creditors in full settlement of their account.
(ii) Investments were sold at a profit of 20% on its book value.
(iii) Full amount was collected from debtors.
(iv) Stock was taken over by Rishika at 50% discount.
(v) Actual expenses of realisation amounted to ₹ 2,00,000 which were paid by the firm. Prepare Realisation Account.- CBSE CLASS XII - 2025
- Dissolution of Partnership Firm
- Your school is organizing an Inter-House Science Model-Making Competition. As President of the Science Club, draft a notice to inform all House members from IX – XII about the competition and specify the number of registrations invited per house. Include other necessary details. You are Mitali/Mukesh. Put your notice in a box.
- CBSE CLASS XII - 2025
- Letter Writing
- The work function of a material is 2.21 eV. Which of the following cannot produce photoelectrons from it?
- CBSE CLASS XII - 2025
- Photoelectric Effect
A carpenter needs to make a wooden cuboidal box, closed from all sides, which has a square base and fixed volume. Since he is short of the paint required to paint the box on completion, he wants the surface area to be minimum.
On the basis of the above information, answer the following questions :
Find \( \frac{dS}{dx} \).- CBSE CLASS XII - 2025
- Differentiation
- A charge \( -6 \mu C \) is placed at the center B of a semicircle of radius 5 cm, as shown in the figure. An equal and opposite charge is placed at point D at a distance of 10 cm from B. A charge \( +5 \mu C \) is moved from point ‘C’ to point ‘A’ along the circumference. Calculate the work done on the charge.
- CBSE CLASS XII - 2025
- Electrostatics
Concepts Used:
Amines
Amine is a type of compound which is derived from ammonia (NH3). According to Organic chemistry, they are basically classified as the functional groups of the organic nitrogen compounds that contain nitrogen atoms with a lone pair.
Amine - Types
Primary Amines:
It is formed when one hydrogen atom in ammonia is substituted by an alkyl or aromatic group. Amino acids and methyl amine are the best examples that why aromatic amines include aniline.
Secondary Amines:
Amines that have two organic substitutes either alkyl or aryl ones or both and are bound to the nitrogen together with one hydrogen are termed as secondary amines. For Example, Dimethylamine.
Tertiary Amines:
Tertiary Amines are the amines where the nitrogen consists of three organic substitutes. For example, Trimethylamine and EDTA.