Accomplish the following conversions:
(i) Nitrobenzene to benzoic acid
(ii) Benzene to m-bromophenol
(iii) Benzoic acid to aniline
(iv) Aniline to 2,4,6-tribromofluorobenzene
(v) Benzyl chloride to 2-phenylethanamine
(vi) Chlorobenzene to p-chloroaniline
(vii) Aniline to p-bromoaniline
(viii) Benzamide to toluene
(ix) Aniline to benzyl alcohol.
Accomplish the following conversions:
(i) Nitrobenzene to benzoic acid
(ii) Benzene to m-bromophenol
(iii) Benzoic acid to aniline
(iv) Aniline to 2,4,6-tribromofluorobenzene
(v) Benzyl chloride to 2-phenylethanamine
(vi) Chlorobenzene to p-chloroaniline
(vii) Aniline to p-bromoaniline
(viii) Benzamide to toluene
(ix) Aniline to benzyl alcohol.
Solution and Explanation
Top Questions on Amines
- An organic compound (P) on treatment with aqueous ammonia under hot condition forms compound (Q) which on heating with Br₂ and KOH forms compound (R) having molecular formula C₆H₇N. Names of P, Q and R respectively are.
- Benzene undergoes the following sequence of reactions:
- Statement-I : $\text{KMnO}_4 \xrightarrow{\Delta} \text{NH}_2$ followed by $\text{Br}_2/\text{KOH} \rightarrow \text{NH}_2$.
Statement-II : $\text{CH}_3\text{NH}_2 \xrightarrow{(i) \text{ Br}_2/\text{H}_2\text{O}, (ii) \text{ NaNO}_2/\text{HCl}, (iii) \text{ H}_3\text{PO}_2/\Delta} \text{CH}_3\text{Br}$. - Which of the following reaction is correctly matched with their product ?
- Observe the following reaction sequence:
\text{(P) }\xrightarrow{\text{NH}_3, \Delta} \text{(Q)} \xrightarrow{\text{Br}_2, \text{KOH}} \text{(R)}
Which of the following is the correct structure for P, Q, and R?
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Concepts Used:
Amines
Amine is a type of compound which is derived from ammonia (NH3). According to Organic chemistry, they are basically classified as the functional groups of the organic nitrogen compounds that contain nitrogen atoms with a lone pair.
Amine - Types
Primary Amines:
It is formed when one hydrogen atom in ammonia is substituted by an alkyl or aromatic group. Amino acids and methyl amine are the best examples that why aromatic amines include aniline.
Secondary Amines:
Amines that have two organic substitutes either alkyl or aryl ones or both and are bound to the nitrogen together with one hydrogen are termed as secondary amines. For Example, Dimethylamine.
Tertiary Amines:
Tertiary Amines are the amines where the nitrogen consists of three organic substitutes. For example, Trimethylamine and EDTA.