We are given the mass of ethyl alcohol and water, and we need to calculate the percentage by mass of ethyl alcohol in the solution:
Mass of ethyl alcohol = 1 mole × MM
$$ \Rightarrow 46 \, \text{g} $$Mass of water = 9 moles × MM
$$ \Rightarrow 162 \, \text{g} $$The percentage by mass of ethyl alcohol is given by:
$$ \% \, \text{by mass of ethyl alcohol} = \frac{46}{162 + 46} \times 100 $$ $$ \Rightarrow 22\% \, (\text{approx.}) $$Thus, the percentage by mass of ethyl alcohol is approximately 22%.
Step 1: Calculate the mass of ethyl alcohol and water
\[ \text{Mass of ethyl alcohol} = 1 \, \text{mole} \times 46 \, \text{g mol}^{-1} = 46 \, \text{g}. \]
\[ \text{Mass of water} = 9 \, \text{mole} \times 18 \, \text{g mol}^{-1} = 162 \, \text{g}. \]
Step 2: Calculate total mass of solution
\[ \text{Total mass of solution} = \text{Mass of ethyl alcohol} + \text{Mass of water} = 46 + 162 = 208 \, \text{g}. \]
Step 3: Calculate mass percent of ethyl alcohol
\[ \text{Mass percent of ethyl alcohol} = \frac{\text{Mass of ethyl alcohol}}{\text{Total mass of solution}} \times 100. \]
\[ \text{Mass percent} = \frac{46}{208} \times 100 = 22.11\%. \]
Final Answer: 22
A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol$^{-1}$) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is $____________ \(\times 10^{-2}\). (nearest integer)
[Given : $K_{b}$ of the solvent = 5.0 K kg mol$^{-1}$]
Assume the solution to be dilute and no association or dissociation of X takes place in solution.