Question:

A solution contains 4 g of NaOH and 16.2 g of water. The mole fraction solute and solvent are respectively

Updated On: Apr 13, 2025
  • 0.1, 0.9
  • 0.2, 0.8
  • 0.5, 0.5

  • 0.4, 0.6
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The Correct Option is A

Solution and Explanation

Answer (A) 0.1, 0.9 

To calculate the mole fraction of a solute and solvent in a solution, we need to determine the number of moles of each component.

Given:

  • Mass of NaOH = 4 g
  • Mass of water = 16.2 g

Step 1: To find the number of moles of NaOH, we divide the given mass by the molar mass of NaOH. The molar mass of NaOH is:

Molar mass of NaOH = 22.99 g/mol (for Na) + 16.00 g/mol (for O) + 1.01 g/mol (for H) = 39.99 g/mol

Number of moles of NaOH = \( \frac{4\ \text{g}}{39.99\ \text{g/mol}} \) ≈ 0.1 mol

Step 2: To find the number of moles of water, we divide the given mass by the molar mass of water. The molar mass of water (H₂O) is:

Molar mass of H₂O = 1.01 g/mol (for H) + 1.01 g/mol (for H) + 16.00 g/mol (for O) = 18.02 g/mol

Number of moles of water = \( \frac{16.2\ \text{g}}{18.02\ \text{g/mol}} \) ≈ 0.9 mol

Step 3: Now, we can calculate the mole fraction of solute (NaOH) and solvent (water):

Mole fraction of solute (NaOH) = \( \frac{\text{Moles of NaOH}}{\text{Total moles}} = \frac{0.1\ \text{mol}}{(0.1\ \text{mol} + 0.9\ \text{mol})} = 0.1 \)

Mole fraction of solvent (water) = \( \frac{\text{Moles of water}}{\text{Total moles}} = \frac{0.9\ \text{mol}}{(0.1\ \text{mol} + 0.9\ \text{mol})} = 0.9 \)

Therefore, the mole fraction of solute (NaOH) and solvent (water) in the given solution are approximately 0.1 and 0.9, respectively. So the correct option is 0.1, 0.9.

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Concepts Used:

Concentration of Solutions

It is the amount of solute present in one liter of solution.

Concentration in Parts Per Million - The parts of a component per million parts (106) of the solution.

Mass Percentage - When the concentration is expressed as the percent of one component in the solution by mass it is called mass percentage (w/w).

Volume Percentage - Sometimes we express the concentration as a percent of one component in the solution by volume, it is then called as volume percentage

Mass by Volume Percentage - It is defined as the mass of a solute dissolved per 100mL of the solution.

Molarity - One of the most commonly used methods for expressing the concentrations is molarity. It is the number of moles of solute dissolved in one litre of a solution.

Molality - Molality represents the concentration regarding moles of solute and the mass of solvent.

Normality - It is the number of gram equivalents of solute present in one liter of the solution and it is denoted by N.

Formality - It is the number of gram formula present in one litre of solution.