To calculate the mass percentage of the solute, we use the formula:
\[
\text{Mass percentage of solute} = \left( \frac{\text{Mass of solute}}{\text{Mass of solution}} \right) \times 100
\]
Where:
- Mass of solute = 4 g
- Mass of solvent (ethanol) = 46 g
- Mass of solution = Mass of solute + Mass of solvent = 4 g + 46 g = 50 g
Now, substituting these values:
\[
\text{Mass percentage of solute} = \left( \frac{4}{50} \right) \times 100 = 8\%
\]
Thus, the correct answer is 8\% (1).