Derivation of Impedance
The total voltage in a series R-C circuit is given by: \[ v = v_R + v_C, \] where: $v_R = i R$ is the voltage across the resistor, $v_C = i \frac{1}{j\omega C}$ is the voltage across the capacitor. The current in the circuit is the same through all components, and the impedance $Z$ of the circuit is given by: \[ Z = \frac{v}{i}. \] The impedance of the resistor is purely real, $Z_R = R$, and the impedance of the capacitor is purely imaginary, $Z_C = -j\frac{1}{\omega C}$. The total impedance is: \[ Z = Z_R + Z_C = R - j\frac{1}{\omega C}. \] The magnitude of the impedance is: \[ |Z| = \sqrt{\text{Re}(Z)^2 + \text{Im}(Z)^2}. \] Substituting the real and imaginary parts: \[ |Z| = \sqrt{R^2 + \left(-\frac{1}{\omega C}\right)^2} = \sqrt{R^2 + \frac{1}{\omega^2 C^2}}. \] Thus, the impedance of the circuit is: \[ Z = \sqrt{R^2 + \frac{1}{\omega^2 C^2}}. \]
A certain reaction is 50 complete in 20 minutes at 300 K and the same reaction is 50 complete in 5 minutes at 350 K. Calculate the activation energy if it is a first order reaction. Given: \[ R = 8.314 \, \text{J K}^{-1} \, \text{mol}^{-1}, \quad \log 4 = 0.602 \]