Step 1: Let the thermal conductivity of copper be \(K_C = 4K\), and that of brass be \(K_B = K\).
Let \(T\) be the temperature at the interface. Since both cubes have equal cross-sectional area and equal length, and the system is in steady-state, the rate of heat flow through both materials is the same.
\[
\frac{K_C (100 - T)}{L} = \frac{K_B (T - 0)}{L}
\Rightarrow 4(100 - T) = T
\Rightarrow 400 - 4T = T
\Rightarrow 5T = 400
\Rightarrow T = 80^\circ \text{C}
\]
% Final Answer
\[
\boxed{80^\circ \text{C}}
\]