Derivation of Refractive Index of the Prism
When a ray of light is incident normally on a refracting face of a prism, the angle of incidence $i = 0$, and the ray enters the prism without deviation. Inside the prism, the ray undergoes refraction at the second face, resulting in a total deviation angle $\delta$. Using the geometry of the prism: \[ \delta = i_e - i_r, \] where: $i_e$ is the angle of emergence, $i_r$ is the angle of refraction inside the prism. From Snell's law at the second face: \[ n = \frac{\sin i_e}{\sin i_r}. \] At the point of minimum deviation ($\delta = \delta_m$), the angles of incidence and emergence are equal: \[ i_e = A + \frac{\delta}{2}. \] Substituting: \[ n = \frac{\sin(A + \delta)}{\sin A}. \] Thus, the refractive index of the prism is: \[ \boxed{n = \frac{\sin(A + \delta)}{\sin A}}. \]
A certain reaction is 50 complete in 20 minutes at 300 K and the same reaction is 50 complete in 5 minutes at 350 K. Calculate the activation energy if it is a first order reaction. Given: \[ R = 8.314 \, \text{J K}^{-1} \, \text{mol}^{-1}, \quad \log 4 = 0.602 \]