Step 1: Compute the direction vector of the line \( L \) The direction ratios of the line passing through points \( (1,2,-3) \) and \( (3,3,-1) \) are: \( \mathbf{d} = (3-1, 3-2, -1+3) = (2,1,2). \)
Step 2: Compute the normal vector of the plane \( \pi \) The normal vector of the plane is found using the cross product of vectors formed by the three given points: \( \mathbf{N} = (2,1,-2), (-2,-3,6), (0,2,-1). \) Solving the determinant gives: \( \mathbf{N} = (1, 4, -8). \)
Step 3: Compute \( \cos \theta \) The angle between a line and a plane satisfies: \( \cos \theta = \frac{|\mathbf{d} \cdot \mathbf{N}|}{|\mathbf{d}||\mathbf{N}|}. \) Computing the dot product: \( \mathbf{d} \cdot \mathbf{N} = (2)(1) + (1)(4) + (2)(-8) = 2 + 4 - 16 = -10. \) Finding magnitudes: \( |\mathbf{d}| = \sqrt{2^2 + 1^2 + 2^2} = \sqrt{9} = 3. \) \( |\mathbf{N}| = \sqrt{1^2 + 4^2 + (-8)^2} = \sqrt{81} = 9. \) \( \cos \theta = \frac{10}{27}. \)
Step 4: Compute \( 27 \cos^2 \theta \) \( 27 \cos^2 \theta = 27 \times \left(\frac{10}{27}\right)^2 = 2. \)
Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))