The degrees of freedom, \( f \), for a gas particle with 3 translational and 3 rotational degrees of freedom is:
\[ f = 3 \, (\text{translational}) + 3 \, (\text{rotational}) = 6. \]
The specific heat ratio \( \gamma \) is given by:
\[ \gamma = \frac{C_P}{C_V} = 1 + \frac{2}{f}. \]
Substitute \( f = 6 \) into the formula:
\[ \gamma = 1 + \frac{2}{6} = 1 + \frac{1}{3} = \frac{4}{3}. \]
Thus, the ratio \( \frac{C_P}{C_V} \) for the gas is \( \frac{4}{3} \).
