The mean free path \( \lambda \) is the average distance a particle can travel before colliding with another particle. The mean free path is inversely proportional to the number density \( n \) (the number of particles per unit volume) and the cross-sectional area of the particles. The formula for the mean free path is given by:
\[
\lambda \propto \frac{1}{n \cdot \sigma}
\]
where \( \sigma \) is the effective collision cross-section of the particles, which is proportional to the square of the particle diameter \( d \).
Thus, the mean free path is inversely proportional to \( d \), the diameter of the particles, as given in option (C).