A chemical plant has four tanks (A, B, C, D), each containing $1000$ litres. Chemical is pumped between tanks at the given rates:
A → B: 20 L/min,
C → A: 90 L/min,
A → D: 10 L/min,
C → D: 50 L/min,
B → C: 100 L/min,
D → B: 110 L/min.
Which tank empties first and how long does it take (minutes) after pumping starts?