Question:

A certain compound X when treated with copper sulphate solution yields a brown precipitate. On adding hypo solution, the precipitate turns white. The compoundXis

Updated On: Aug 3, 2024
  • $K_2CO_3$
  • KI
  • KBr
  • $K_3PO_4$
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The Correct Option is B

Solution and Explanation

When potassium iodide is reacted with CuS04,
it gives iodine gas which is brown colour. This
iodine react with sodium thiosulphate and form
white precipitate of sodium tetrathionate.
$2CuSO_4 \, + \, 4 KI \, \longrightarrow \, K_2 SO_4 \, + \, I_2 \, + 2CuI$
$ 2Na_2S_2O_3 \, + \, I_2 \, \longrightarrow \, Na_2S_4O_6 \, + \, 2NaI $
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Concepts Used:

Group 17 Elements

Halogens are the group 17 elements of the periodic table. The term ‘halogen’ means ‘salt-producing’, hence the name halogens as they possess the tendency to form salts after reacting to metals. It generally has five elements:

  • Fluorine (F)
  • Chlorine (Cl)
  • Bromine (Br)
  • Iodine (I)
  • Astatine (At)

These are all naturally occurring halogens but Tennessine (Ts) is an artificially created halogen.

Halogens:

Halogens are highly reactive elements and are highly electronegative. They have a high tendency to react with metals to form salts. They are also known as Group 17 elements. They have 7 electrons in their outer shell with a configuration of (ns2 np5). Fluorine being the first halogen in group 17, is highly reactive. Astatine is a halogen because of its resemblance with iodine despite it being radioactive.

Electronic Configuration:

The general electronic configuration for group 17 elements is ns2np5. This configuration clearly shows that they have 7 electrons in their valence shell. They require one more electron to complete their octet and achieve noble gas configuration.