Let the probability of number \( k \) appearing be proportional to \( k^2 \). So, the probability of rolling \( k \) is \( P(k) = \frac{k^2}{\sum_{k=1}^6 k^2} \).
First, calculate the sum of the squares of the numbers from 1 to 6:
\[
\sum_{k=1}^6 k^2 = 1^2 + 2^2 + 3^2 + 4^2 + 5^2 + 6^2 = 1 + 4 + 9 + 16 + 25 + 36 = 91.
\]
Thus, the probability of rolling an even number (i.e., \( k = 2, 4, 6 \)) is:
\[
P(\text{even}) = P(2) + P(4) + P(6) = \frac{2^2}{91} + \frac{4^2}{91} + \frac{6^2}{91} = \frac{4 + 16 + 36}{91} = \frac{56}{91}.
\]
Therefore, the probability that an even number will appear is \( \frac{56}{91} \).
Final Answer:
\[
\boxed{(B) \, \frac{56}{91}.}
\]