Question:

4f2 electronic configuration is found in

Updated On: Apr 11, 2025
  • Pr
  • Pr3+
  • Nd3+
  • Pm3+
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The Correct Option is B

Solution and Explanation

The electronic configuration 4f2 corresponds to the ion Pr3+, which is derived from the element Praseodymium (Pr).

Neutral Praseodymium (Pr) has the atomic number 59, and its ground state electronic configuration is: 

[Xe] 4f3 6s2

When it forms the ion Pr3+, three electrons are removed. These are typically removed first from the outermost orbitals (6s and 4f):

  • Two electrons from the 6s orbital
  • One electron from the 4f orbital

This leaves the configuration as [Xe] 4f2.

Therefore, the correct answer is option (B): Pr3+

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Concepts Used:

Lanthanoids

Lanthanoids are at the top of these two-row, while actinoids are at the bottom row.

Properties of Lanthanoids

Lanthanoids are inclusive of 14 elements, with atomic numbers 58-71:

  • Cerium - Xe 4f1 5d1 6s2
  • Praseodymium - Xe 4f3 6s2
  • Neodymium - Xe 4f4 6s2
  • Promethium - Xe 4f5 6s2
  • Samarium - Xe 4f6 6s2
  • Europium - Xe 4f7 6s2
  • Gadolinium - Xe 4f7 5d1 6s2
  • Terbium - Xe 4f9 6s2
  • Dysprosium - Xe 4f10 6s2
  • Holmium - Xe 4f11 6s2
  • Erbium - Xe 4f12 6s2
  • Thulium - Xe 4f13 6s2
  • Ytterbium - Xe 4f14 6s2
  • Lutetium - Xe 4f14 5d1 6s2

These elements are also called rare earth elements. They are found naturally on the earth, and they're all radioactively stable except promethium, which is radioactive. A trend is one of the interesting properties of the lanthanoid elements, called lanthanide contraction.