\(2HC = CH_2\text{Cl}_2 \xrightarrow{\text{A}} \text{NH}_4\text{Cl}\)\(\xrightarrow{\text{B}}\)\(\text{Identify the compounds A and B}\)
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In organic reactions, identifying the reaction mechanism (like nucleophilic substitution or elimination) helps in predicting the structures of the intermediates and products.
The given reaction involves a compound that undergoes a transformation with ammonia and hydrochloric acid. Based on the reaction and structure of the products, compound A corresponds to a conjugated alkene, and compound B is a substituted product of a vinyl chloride derivative.
Thus, the correct structure for compounds A and B corresponds to option (a).