Question:

When phenol is treated with NaOH, CO_2 (heat), and then acidified, what results?

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The Kolbe-Schmitt reaction involves phenol, NaOH, CO\(_2\), and acidification to form salicylic acid.
  • Benzoic acid
  • Salicylic acid
  • Benzene
  • Anisole
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The Correct Option is B

Solution and Explanation

Step 1: Understanding the reaction.
This reaction is known as the Kolbe-Schmitt reaction. In this reaction, phenol reacts with sodium hydroxide (NaOH) and carbon dioxide (CO\(_2\)) at high temperature to form the sodium salt of salicylic acid. Upon acidification, the sodium salt is converted into salicylic acid.
Step 2: Conclusion.
The correct product of this reaction is salicylic acid, which corresponds to option (B).
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