Let I=\(\int_{0}^{1} x(1-x)^n \,dx\)
∴I=\(\int_{0}^{1} (1-x)(1-(1-x))^n \,dx\)
=\(\int_{0}^{1} x(1-x) (x)^n \,dx\)
\(=∫^1_0(x^n-x^{n+1})dx\)
\(=[\frac{x^{n+1}}{n+1}-\frac{x^{n+2}}{n+2}]\,\,\,\,\, (∫^a_0ƒ(x)dx=∫^a_0ƒ(a-x)dx)\)
=\([\frac{1}{n+1}-\frac{1}{n+2}]\)
=\(\frac{(n+2)-(n+1)}{(n+1)(n+2)}\)
=\(\frac{1}{(n+1)(n+2)}\)
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.