For real gases, the relation between $P$, $V$ and $T$ is given by van der Waals equation, $\left(P+\frac{an^{2}}{V^{2}}\right) \left(V-nb\right)=nRT$. For the following gases $CH_4$, $CO_2$, $O_2$ $H_2$ which gas will have (i) highest value of $a$ (ii) lowest value of $b$ ?