The standard reduction potentials of \(2H^+ / H_2\), \(Cu^{2+} / Cu\), \(Zn^{2+} / Zn\), and \(NO_3^- / HNO_2\) are 0.0, +0.34, -0.76, and +0.97 V respectively. Observe the following reactions:
I. \( Zn + HCl \rightarrow \)
II. \( Cu + HCl \rightarrow \)
III. \( Cu + HNO_3 \rightarrow \)
Which reactions do not liberate \(H_2\) gas?