For the Daniel cell, $Zn\left| Zn^{2+}\right|\left| Cu^{2+}\right| Cu$ with $E_{\text{cell}} = 1 . 1\, V$, the application of opposite potential greater than $1 . 1\, V$ results into flow of electron from cathode to anode.
$Zn$ is deposited at anode and $Cu$ is dissolved at cathode.